The team composition for the Curtain Raiser match is as follows:
| South Team Stars | Mumbai Team Stars |
| Venkatesh (Captain) | Salman Khan |
| Suriya | Suneel Shetty |
| Sudeep (Vice Captain) | Riteish Deshmukh |
| Sharat Kumar | Sohail Khan |
| Manchu Vishnu | Arbaaz Khan |
| Siddharth | Sonu Sood |
| Tarun | Harman Baweja |
| Taraka Ratna | Kabir Sadanand |
| Abbas | Shabbir Ahluwalia |
| Arya | Angad Bedi |
| Shaam | Apoorva Lakhia |
| Chiranjeevi Srja | Aashish Chowdhry |
| Dhruv | Vikas Kalantri |
| Vikrant | Ankush Choudhary |
| Shantanu Bhagyaraj | |
| Ambassadors | Ambassadors |
| Shriya Sharan, Priyamani, Charmi, Tapsee, Samantha, Andrita, Ragini | Genelia, Sonakshi Sinha |
